The former Germany worldwide was fielded out on loan to Sevilla, Fiorentina and Anderlecht before heading to Turkish side Trabzonspor last season.
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Marin was on the field for just 143 Premier League minutes during his time with Chelsea. Besiktas have also been linked with a move for Marko Marin according to Fotomac.
Marin made 13 appearances in his first season at Chelsea but in the 2013/14 campaign was shipped out to Spain when Jose Mourinho took over as manager.
Juventus are confident of signing the Colombia global before the end of this week.
Speaking about the move, Marin told Greek outlet Sport 24: “I know very well that I have come to a great club with great history. It is also nice to sign a permanent deal on a three-year contract”.
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Olympiacos would be delighted to have captured Marko Marin who would serve as a replacement for Jimmy Durmaz, who left the club for Ligue 1 side Toulouse.
